During the 20th century, amatol , a mixture of TNT with ammonium nitrate was a widely used military explosive. The diamino products are energetically less favorable, and even less likely are the triamino products. Even small quantities of such impurities can cause such effect. The heat of combustion is There is evidence that TNT adversely affects male fertility.
Exudation of impurities leads to formation of pores and cracks which in turn cause increased shock sensitivity. Therefore, when considering the adsorption of TNT, the type of soil or sediment and the ionic composition and strength of the ground water are important factors. TNT is prone to exudation of dinitrotoluenes and other isomers of trinitrotoluene. Upon detonation , TNT decomposes as follows: An organism capable of the remediation of large amounts of TNT in soil has yet to be discovered. However, when salinity was altered, TNT dissolved at the same speed Figure 2. The relatively low aqueous solubility of TNT causes the dissolution of solid particles to be continuously released to the environment over extended periods of time. There is evidence that TNT adversely affects male fertility. Blood and liver effects, spleen enlargement and other harmful effects on the immune system have also been found in animals that ingested or breathed trinitrotoluene. The transformation of TNT is significantly enhanced under anaerobic conditions as well as under highly reducing conditions. Wastewater from munitions programs including contamination of surface and subsurface waters may be colored pink because of the presence of TNT. TNT can be detonated with a high velocity initiator or by efficient concussion. Even small quantities of such impurities can cause such effect. The alteration of a molecule in photolysis occurs in the presence of direct absorption of light energy by the transfer of energy from a photosensitized compound. The reference has since been changed to a more sensitive explosive called RDX , which has an F of I rating of TNT and its transformation products are known to adsorb to surface soils and sediments, where they undergo reactive transformation or remained stored. Photolysis was more rapid in river water than in distilled water. Formation of the two monoamino transformation products, 2-ADNT and 4-ADNT are energetically favored, and therefore are observed in contaminated soils and ground water. Soils with high clay contents or small particle sizes and high total organic carbon content have been shown to promote TNT transformation. Migration of the exudated liquid into the fuze screw thread can form fire channels, increasing the risk of accidental detonations; fuze malfunction can result from the liquids migrating into its mechanism. The effect shows especially in projectiles containing TNT and stored at higher temperatures, e. During the 20th century, amatol , a mixture of TNT with ammonium nitrate was a widely used military explosive. Clay minerals have a significant effect on the adsorption of energetic compounds. The heat of combustion is Materials that associate strongly with soils move slowly through soil.
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